期刊
TETRAHEDRON LETTERS
卷 44, 期 50, 页码 8991-8994出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2003.10.002
关键词
Baeyer Villiger reaction; cyclic ketones; lactones; ionic liquids; [bmim]BF4-
The Baeyer-Villiger oxidation of cyclic ketones can be effected by methyltrioxorhenium/hydrogen peroxide in the ionic liquid [bmim]BF4. After simple extraction of the lactone with diethyl ether, the catalyst can be repeatedly recycled and efficiently reused for the lactonisation process in the same reaction medium. (C) 2003 Elsevier Ltd. All rights reserved.
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