期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 688, 期 1-2, 页码 144-152出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2003.07.026
关键词
antimalarial activity; heterobimetallic complexes; chloroquine
The reaction of chloroquine and several ferrocenyl derivatives of chloroquine with Au(PPh3)NO3, Au(C6F5)(tht) and [Rh(COD)Cl](2) have been investigated. The resulting products have been characterised by a range of techniques including NMR, mass spectrometry, elemental analysis, IR and cyclic voltammetry. The data suggests that the products are heterobimetallic complexes where the quinoline nitrogen coordinates to the Au or Rh. In vitro studies against Plasmodium falciparum are reported. (C) 2003 Elsevier B.V. All rights reserved.
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