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Acid catalysis by heteropoly acids

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APPLIED CATALYSIS A-GENERAL
卷 256, 期 1-2, 页码 19-35

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DOI: 10.1016/S0926-860X(03)00386-7

关键词

heteropoly acid; Keggin-type structure; Dawson-type structure; acidity; Hammet acidity function; acetone dimerization to mesitylene oxide; acetic acid and n-butyl alcohol esterification; L-sorbose acetonation

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The achievements in the field of acid catalysis by heteropoly acids having different structures HXPW11LO40 (L = Zr-IV, Ti-IV, Th-IV) H(X)ZW(12)O(40) (Z = Si-IV, P-V, B-III, Co-III, Ge-IV), H21B3W39O132, H6P2W18O62, H6P2W21O71, H6As2W21O69 are reviewed. The data on the acidity of HPAs are generalized. The rules of homogeneous and heterogeneous acid catalysis by HPAs are discussed. (C) 2003 Published by Elsevier B.V.

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