期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 689, 期 1, 页码 3-7出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2003.09.025
关键词
diastereoselective; C-H bond activation; heterochelate PN ligand; cationic; iridium
Highly diastereoselective intramolecular C-H bond activation at a prochiral sp(3) carbon was achieved with a cationic iridium complex having an optically active heterochelate PN*(R) [PN*(R) = o-Ph2PC6H4CH2OCH2C=NCH(R)CH2O] ligand. (C) 2003 Elsevier B.V. All rights reserved.
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