4.5 Article

Conversion of alcohols, thiols, carboxylic acids, trimethylsilyl ethers, and carboxylates to thiocyanates with triphenylphosphine/diethylazodicarboxylate/NH4SCN

期刊

SYNTHESIS-STUTTGART
卷 -, 期 1, 页码 92-96

出版社

GEORG THIEME VERLAG KG
DOI: 10.1055/s-2003-44369

关键词

triphenylphosphine; diethylazodicarboxylate; thiocyanation; alcohol; thiol; carboxylic acid; silyl ether; silyl carboxylate

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A novel and highly selective method is described using triphenylphosphine/diethylazodicarboxylate (DEAD)/NH4SCN for the conversion of alcohols, thiols, carboxylic acids, silyl ethers, and silyl carboxylates to their corresponding thiocyanates.

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