4.7 Article

Simple synthesis of substituted pyrroles

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JOURNAL OF ORGANIC CHEMISTRY
卷 69, 期 1, 页码 213-216

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AMER CHEMICAL SOC
DOI: 10.1021/jo035200i

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  1. NCI NIH HHS [5-P30-CA16672-25] Funding Source: Medline

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Simple synthesis of substituted pyrroles using iodine-catalyzed and montmorillonite KSF-clay-induced modified Paal-Knorr methods has been accomplished with excellent yields. N-Substituted carbazole has also been prepared by following this method. If one of the reactants is a liquid, the reaction proceeds exceedingly well without a solvent. This method gives pyrroles with less nucleophilic multicyclic aromatic amines at room temperature.

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