期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 126, 期 2, 页码 683-692出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja034444h
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Quantum-chemical methods are applied to study the nature of the excited states relevant in the photophysical processes (absorption and emission) of a series of polyazaaromatic-ligand-based ruthenium(11) complexes. The electronic and optical properties of the free polyazaaromatic ligands and their corresponding ruthenium(II) complexes are determined on the basis of correlated Hartree-Fock semiempirical approaches'. While the emission of complexes containing small-size ligands, such as 1,10-phenanthroline or 2,2'-bipyridine, arises from a manifold of metal-to-ligand charge-transfer triplet states ((MLCTs)-M-3), an additional ligand-centered triplet state (L-3) is identified in the triplet manifold of complexes containing a pi-extended ligand such as dipyrido[3,2-a:2',3-c]phenazine, tetrapyrido[3,2-a:2',3'-c:3,2-h: 2''',3'''-j]phenazine, and 1,10-phenanthrolino[5,6-b]-1,4,5,8,9,12-hexaazatriphenylene. Recent experimental data are interpreted in light of these theoretical results; namely, the origin for the abnormal solvent- and temperature-dependent emission measured in pi-extended Ru complexes is revisited.
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