期刊
SYNTHETIC COMMUNICATIONS
卷 34, 期 4, 页码 599-605出版社
TAYLOR & FRANCIS INC
DOI: 10.1081/SCC-120027707
关键词
oximes; amines; ammonium formate; hydrogenation; magnesium powder
Various aldoximes and ketoximes were selectively reduced to the corresponding amines by catalytic transfer hydrogenation employing low cost magnesium powder and ammonium formate at room temperature. Many other functionalities such as halogens, -OH, -OCH3, -COOH and -CH3 remained unaffected. The hydrogenation is fast, mild, clean, cost effective and high yielding.
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