4.4 Review

Catalytic transformations of the major terpene feedstocks

期刊

TOPICS IN CATALYSIS
卷 27, 期 1-4, 页码 143-155

出版社

SPRINGER/PLENUM PUBLISHERS
DOI: 10.1023/B:TOCA.0000013549.60930.da

关键词

catalysis; terpene; hydrogenation; hydrogenolysis; dehydrogenation; rearrangement; isomerization; aromatization; epoxidation; turpentine; monoterpene; pinene; limonene; carene; geraniol; citronellol; citral; citronellal

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A review covering some of the key catalytic transformations of the major monoterpene feedstocks. Monoterpenes are key ingredients in the flavor and fragrance industry, with alpha- and beta-pinene (obtained from turpentine) being some of the most important. The review focuses on the hydrocarbons; pinene, limonene, carene, and the interconversion of the monooxygenates; geraniol/nerol, citronellol, citral, and citronellal. The major areas covered are catalytic hydrogenation/hydrogenolysis, dehydrogenation, rearrangement/isomerization/aromatization, reactions with carbon monoxide, epoxidation, and the addition of alcohols and acids.

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