期刊
TETRAHEDRON
卷 60, 期 6, 页码 1287-1291出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2003.10.063
关键词
catalysis; Zr complexes; organomagnesium compounds; cyclomagnesiation; carbomagnesiation; 1,2-dienes; deuterolysis
Cyclo- and carbomagnesiation of 1,2-dienes with EtMgR' (R'=Et, Br) in the presence Of CP2ZrCl2 catalyst lead to alkylidenemagnesiocyclopentanes. Deuterolysis provides insights into the reaction pathways. (C) 2003 Elsevier Ltd. All rights reserved.
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