期刊
JOURNAL OF CATALYSIS
卷 222, 期 1, 页码 255-259出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2003.10.029
关键词
metal sulfate catalyst; oxidation; hydration; sulfur resistance
Hydration of manganese sulfate at a low reaction temperature (150 degreesC) induces high heterogeneous catalytic activity and stability in the oxidation of methanethiol. The temperature of the reaction controls the reversible change of structure, i.e., hydration/dehydration processes as well as the associated changes of activity and selectivity. (C) 2003 Elsevier Inc. All rights reserved.
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