期刊
APPLIED SURFACE SCIENCE
卷 223, 期 1-3, 页码 49-53出版社
ELSEVIER
DOI: 10.1016/S0169-4332(03)00897-3
关键词
combinatorial approach; powder synthesis; ramsdellite-type structure
Pseudo-ternary compounds of LiO0.5-X-TiO2 (X: FeO1.5, CrO1.5 and NiO) system were prepared using a fully automatic combinatorial robot system with the following functions: weighing and mixing of starting materials, heat treatment, and X-ray diffraction analysis. The following crystal structures were obtained by means of heat treatment at 1373 K: ramsdellite, spinel, pseudobrookite, rock salt, hematite and rutile. Furthermore, the composition range of the products with a ramsdellite-type structure in LiO0.5-X-TiO2 (X: FeO1.5, CrO1.5 and NiO) system was considered to have a relationship to the ionic radii of the substitutional transition metals Fe-,(3+) Cr3+ and Ni2+ for Ti4+ in octahedral site. It was found that solubility limits of 3d elements in lithium titanium oxide with ramsdellite structure were investigated in a shorter time by combinatorial method. (C) 2003 Elsevier B.V. All rights reserved.
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