期刊
ORGANIC LETTERS
卷 6, 期 4, 页码 525-528出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol036284k
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资金
- NCI NIH HHS [CA56304] Funding Source: Medline
The asymmetric synthesis of the fully elaborated macrocyclic core of cytotrienins A-D, potent apoptosis-inducing agents, is described. Synthetic highlights include the construction of the aniline bond using a copper-mediated amidation and the use of a ring-closing metathesis (RCM) reaction to efficiently install the (E,E,E)-triene and simultaneously construct the macrocyclic lactam.
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