期刊
COORDINATION CHEMISTRY REVIEWS
卷 248, 期 5-6, 页码 493-532出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2004.02.001
关键词
binary nitrides; C3N4; Si3N4; synthesis; properties; structures
In recent years, a lot of work has been focused on the synthesis of novel carbon nitrides, especially crystalline C3N4 phases. Numerous attempts to synthesise the theoretically predicted solids have been published. This review summarises the theoretical work as well as the attempts to prepare carbon(IV) nitrides by chemical and physical vapour deposition, and in particular on the concepts and results of bulk synthesis routes. Although very interesting materials have been obtained, a comprehensive characterisation of a crystalline C3N4 phase is still missing. In 1999, a novel class of nitrides, which posses the spinel structure. has been discovered. The synthesis and properties of the high pressure phases gamma-M3N4 with M = Si, Ge and the first tin nitride gamma-Sn3N4 are reviewed. Related oxide nitride spinel compounds, other ternary phases such as Si/C/N as well as subnitrides, sialons and amorphous phases are mentioned briefly. (C) 2004 Published by Elsevier B.V.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据