期刊
JOURNAL OF COMPUTER-AIDED MOLECULAR DESIGN
卷 18, 期 3, 页码 209-214出版社
SPRINGER
DOI: 10.1023/B:JCAM.0000035200.30340.41
关键词
asymmetric synthesis; boranes; cycloadditions; density functional calculations; ligand design
Several chiral vinylboranes have been theoretically evaluated as enantioselective Diels - Alder dienophiles. Theoretical results suggest that optically pure 2,5-diphenyl-1-vinyl-borolane should be the reagent of choice for performing such transformations efficiently.
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