期刊
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
卷 211, 期 1-2, 页码 9-16出版社
ELSEVIER
DOI: 10.1016/j.molcata.2003.09.023
关键词
epoxidation; dioxomolybdenum(VI) complexes of tetradentate Schiff bases; tert-butyl hydroperoxide
Six dioxomolybdenum(VI) complexes of Schiff-bases derivatives of trans-1,2-diaminocyclohexane and R-salicylaldehyde as well as 2-hydroxynaphthaldehyde have been synthesised and characterized by IR, UV-Vis and NMR-spectroscopic methods. The catalytic activities of the complexes in the reaction of epoxidation of cyclohexene and 1-octene with tert-butyl hydroperoxide (TBHP) as oxidant have been studied. (C) 2003 Elsevier B.V. All rights reserved.
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