期刊
COORDINATION CHEMISTRY REVIEWS
卷 248, 期 7-8, 页码 725-756出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2004.03.009
关键词
acetylide complexes; alkynyl complexes; vinylidene complexes; nonlinear optics; hyperpolarizabilities; quadratic nonlinearities; cubic nonlinearities
The nonlinear optical (NLO) properties of metal acetylide and vinylidene complexes are summarized, and molecular structure-NLO property trends are developed. The origin of NLO effects in molecules is presented, and the advantages and shortcomings of experimental procedures that have been used to measure optical nonlinearities for these complexes are discussed. Attempts to switch optical nonlinearities of acetylide or vinylidene complexes are summarized. (C) 2004 Elsevier B.V. All rights reserved.
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