期刊
SURFACE SCIENCE
卷 554, 期 1, 页码 43-59出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.susc.2004.02.008
关键词
sum frequency generation; density functional calculations; palladium; carbon monoxide; hydrogen molecule; alkenes; low index single crystal surfaces; catalysis; vibrations of adsorbed molecules
CO-H interaction and H bulk dissolution on Pd(1 1 1) were studied by sum frequency generation (SFG) vibrational spectroscopy and density functional theory (DFT). The theoretical findings are particularly important to rationalize the experimentally observed mutual site blocking of CO and H and the effect of H dissolution on coadsorbate structures. Dissociative hydrogen adsorption on CO-precovered Pd(1 1 1) is impeded due to an activation barrier of similar to2.5 eV for a CO coverage of 0.75 ML, an effect which is maintained down to 0.33 ML CO. Preadsorbed hydrogen prevented CO adsorption at 100 K, while hydrogen was replaced from the surface by CO above 125 K. The temperature-dependent site blocking of hydrogen originates from the onset of hydrogen diffusion into the I'd bulk around 125 K, as shown by SFG and theoretical calculations using various approaches. When Pd(1 1 1) was exposed to 1:1 CO/H-2 mixtures at 100 K, on-top CO was absent in the SFG spectra although hydrogen occupies only threefold hollow sites on Pd(1 1 1). DFT attributes the absence of on-top CO to H atoms diffusing between hollow sites via bridge sites, thereby destabilizing neighboring on-top CO molecules. According to the calculations, the stretching frequency of bridge-bonded CO with a neighboring bridge-bonded hydrogen atom is redshifted by 16 cm(-1) when compared to bridging CO on the clean surface. Implications of the observed effects on hydrogenation reactions are discussed and compared to the C2H4-H coadsorption system. (C) 2004 Elsevier B.V. All rights reserved.
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