期刊
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
卷 77, 期 4, 页码 709-714出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/bcsj.77.709
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A new zeolite-immobilized copper(II) complex catalyst has been prepared by entrapping [CuL] [LH2 = N,N'-(1,1-dimethylethylene)bis(salicylaldiimine)] on NaY zeolite matrix. The reaction of Cu-NaY and molten LH2 affords a green mass of crude catalyst that upon a treatment with CH3CN gives a gray-colored hybrid catalyst (CuL-NaY). The prepared catalyst has been characterized by IR and UV-vis spectroscopic and EPR spectrometric measurements, TG-DTA analysis. powder X-ray diffraction. and surface-area measurements. To ascertain the structure of the immobilized complex, a single-crystal X-ray diffraction analysis of [CuL] was performed. Spectroscopic measurements showed that the green crude of CuL-NaY contains a penta- or hexa-coordinated copper(II) moiety, while the CuL-NaY catalyst contains a distorted square-planar [CuL] complex moiety. A remarkable catalytic activity of the prepared hybrid catalyst has been observed in oxidation reactions of 1-naphthol and norbornene.
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