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Chlorobis(1,10-phenanthroline)copper(II) perchlorate hemihydrate

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WILEY-BLACKWELL
DOI: 10.1107/S1600536804005306

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The title compound, [CuCl(C12H8N2)(2)]ClO4.0.5H(2)O, was formed from an aqueous solution of Cu(phen)Cl-2 (phen is 1,10-phenanthroline) containing NaClO4 and 2,2'-bipyridyl. The Cu atom is five-coordinated by four N atoms from two 1,10-phenanthroline ligands and by a Cl atom, with a slightly distorted trigonal-bipyramidal stereochemistry. There are two cations, two anions and one water molecule in the asymmetric unit.

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