Effect of alkali and ultraviolet (UV) radiation pretreatment on physical and mechanical properties of 1,6-hexanediol diacrylate-grafted jute yarn by UV radiation

To improve the physicomechanical properties of jute yarn, grafting with 1,6-hexanediol diacrylate (HDDA) monomer was performed by a UV radiation technique. A series of HDDA solutions of various concentrations in methanol were prepared. A small quantity of photoinitiator (Darocur-1664) was also added to HDDA solutions. To optimize the conditions for grafting, the effects of monomer concentration, soaking time, and radiation doses were studied by varying the number of soaking times along with variation of monomer concentrations and UV radiation intensities. The extent of polymer loading and the mechanical properties like tensile strength (TS), elongation at break (Eb), and tensile modulus of both treated and untreated jute were investigated. The highest tensile strength, polymer loading, and modulus were achieved with 5% HDDA concentration, 5 min soaking time, and the 4th pass of UV radiation. This set of conditions was selected as optimum and produced enhanced tensile strength (67%), modulus (108%), and polymer loading (11%) over those of virgin fiber. To further improve the mechanical properties the jute yarns were pretreated with alkali (5% NaOH) solution and after that the alkali-treated yarn were treated under UV radiation of various intensities. The pretreated samples were grafted with optimized monomer concentration (5% HDDA). Increased properties of alkali + UV-pretreated and grafted samples such as polymer loading (12%), tensile strength (103%), elongation at break (46%), and modulus (114%) were achieved over those of virgin jute yarn. (C) 2004 Wiley Periodicals, Inc.