The identity of the metal-organic framework formed by Mn(II) and 4,4'-dicarboxy-2,2'-bipyridine (H(2)dcbp) depends upon the predominant solvent employed in the synthesis and yields the robust network isomers [[Mn(dcbp)].1/2 DMF}(n), 1, and {[Mn(dcbp)].2H(2)O}(n), 2, which possess vastly different physical properties: 1 irretrievably binds DMF, whereas 2 reversibly binds water whilst retaining crystallinity.
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