期刊
TETRAHEDRON LETTERS
卷 45, 期 16, 页码 3313-3315出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2004.02.145
关键词
Tishchenko reaction; Oppenauer oxidation; alpha-silyloxyaldehyde; alpha-silyloxyketone
The aliphatic aldehydes react with catalytic amount of Dibal-H in n-pentane to give the corresponding Tishchenko products in good to excellent yields. Contrary, alpha-silyloxyaldehydes give alpha-silyloxyketones via Oppenauer oxidation under similar condition. (C) 2004 Elsevier Ltd. All rights reserved.
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