期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 10, 期 8, 页码 1913-1919出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200305589
关键词
coordination modes; iron; modular assembly; scanning probe microscopy; supramolecular chemistry
We present a comprehensive investigation of the modular assembly of surface-supported metal-organic coordination systems with specific topologies and high structural stability formed by vapor deposition of 1,4-benzenedicarboxylic acid molecules and iron atoms on a Cu(100) surface under ultra-high vacuum conditions. By making use of the two carboxylate moieties available for lateral linkage to Fe atoms, we succeeded in the fabrication of distinct Fe-carboxylate coordination architectures at the surface by carefully adjusting the ligand and metal concentration ratio and the temperature of the post-deposition annealing treatment. The mononuclear, 1D-polymeric and fully 2D-reticulated metallosupramolecular arrangements obtained were characterized in situ at the single-molecule level by scanning tunneling microscopy.
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