期刊
MATERIALS TRANSACTIONS
卷 45, 期 5, 页码 1607-1612出版社
JAPAN INST METALS
DOI: 10.2320/matertrans.45.1607
关键词
one-pot process; photocatalytic activity; TiO2; titanium; anodic oxide film; antibacterial activity
Thick anodic oxide film with high photocatalytic activity was prepared successfully in 1.5 kmol/m(3) H2SO4-0.3 kmol/m(3) H2O2 with 0.03-0.09 kmol/m(3) H3PO4 in a one-pot process. Increasing H3PO4 concentration in the range of 0-0.3 kmol/m(3d) suppressed spark discharge, resulting in a higher anatase-to-rutile ratio and fewer lower-valent titanium oxides in the anodized films. The photocatalytically active films consisted of a mixture of anatase and rutile crystallites with a small amount of Ti3+ ions, and had very rough surface with a large number of pores with a diameter on the order of micrometers. The film prepared in the 1.5 kmol/m(3) H2SO4-0.3 kmol/m(3) H2O2-0.03 kmol/m(3) H3PO4 dispersed with TiO2 nanoparticles was the most active photocatalytically among the films obtained, and exhibited antibacterial activity.
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