期刊
JOURNAL OF PHYSICAL CHEMISTRY B
卷 108, 期 18, 页码 5771-5777出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp0499575
关键词
-
Solvation and rotational dynamics of coumarin 153 (C153) were measured in a series of phosphonium ionic liquids consisting of the trihexyl(tetradecyl)phosphonium cation and the anions Br-, Cl-, dicyanamide(-), bis(trifluoromethylsulfonyl)imide(-), and BF4-. None of these liquids display a prominent ultrafast solvation component comparable to the one observed in imidizalium ionic liquids. The solvation dynamics observed on the nanosecond time scale are also 5-fold slower than those in imidazolium liquids of comparable viscosities. Both rotation and solvation are highly nonexponential functions of time and can be represented by stretched-exponential decays with exponents near 0.5. Characteristic times of these processes track solvent viscosity. A number of similarities between the dynamics observed in these ionic liquids and supercooled glass-forming liquids are noted.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据