4.7 Article

Two mixed-valence copper(I,II) imidazolate coordination polymers: metal-valence tuning approach for new topological structures

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CHEMICAL COMMUNICATIONS
卷 -, 期 9, 页码 1100-1101

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ROYAL SOC CHEMISTRY
DOI: 10.1039/b401691b

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A new metal-valence tuning synthetic approach has been utilized to generate two new mixed-valence Cu(I,II) coordination polymers Cu-2(im)(3) and Cu-3(im)(4) (Him = imidazole), which are an unprecedented uninodal 4-connected 4.8(5) topological net and a 4-connected (4,4) net, respectively.

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