期刊
ORGANIC LETTERS
卷 6, 期 10, 页码 1601-1603出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol049630m
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资金
- NCI NIH HHS [CA 59703] Funding Source: Medline
Stereoselective synthesis Of D-desosamine diacetate ester (iii, R = Ac) was achieved from the glycal (ii) generated by tungsten carbonyl-catalyzed cycloisomerization of the corresponding amino-alkynol (i). A wide variety of N-substituents (R, R') are compatible with the cycloisomerization, provided that at least one R or R' is an acyl derivative.
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