期刊
JOURNAL OF CHROMATOGRAPHY A
卷 1036, 期 2, 页码 101-111出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.chroma.2004.02.081
关键词
sol-gel technology; solid-phase microextraction; pesticides; organophosphorus compounds; bisbenzo crown ether
Allyloxy bisbenzo 16-crown-5 trimethoxysilane was first used as precursor to prepare the sol-gel-derived bisbenzo crown ether/hydroxyl-terminated silicone oil (OH-TSO) SPME coating. The coating procedure involving sol solution composition and conditioning process was presented. Compared with commercial SPME stationary phases, the new coatings showed higher extraction efficiency and therefore could provide higher sensitivity for organphosphorous pesticides (OPs). Limits of detection (LODs) were in the range of 0.003-1.0 ng/g for these OPs in food samples (honey, juice, orange and pakchoi). The optimal extraction conditions of the new coatings to OPs in these samples were investigated by adjusting extraction time, salt addition, extraction temperature, and dilution ratios of samples with distilled water by using SPME coupled with gas chromatography (GC)-flame photometric detection (FPD). The method was applied to determine the concentrations of OPs in real samples. (C) 2004 Elsevier B.V. All rights reserved.
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