期刊
CHEMICAL COMMUNICATIONS
卷 -, 期 10, 页码 1210-1211出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b402322f
关键词
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(R)- and (S)-gamma-[3-H-2(1)]butyrolactones have been synthesised from (R)- and (S)-glycidol, respectively, and used to demonstrate that it is the pro-(S) hydrogen atom that is stereospecifically abstracted from C-3 of 4-hydroxybutyryl-CoA by 4-hydroxybutyryl-CoA dehydratase, and that this atom is not returned to C-4.
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