期刊
CHEMICAL COMMUNICATIONS
卷 -, 期 10, 页码 1240-1241出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b403491k
关键词
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The 1-phosphanorbornadiene-rhodium complex (Rh-PNBD) anchored on a mesostructured porous silica matrix is the first example of a rhodium center chelated by a phosphorus and an oxygen atom belonging to the anchoring siloxane moiety. These new hybrid silicas behave as very active recyclable hydrogenation catalysts, which combined with additional grafted amino functions allow efficiently driven one-pot bifunctionnal catalysis.
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