期刊
CHEMICAL COMMUNICATIONS
卷 -, 期 10, 页码 1170-1171出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b402686a
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K6Cd4Sn3Se13 forms in superheated water and has a polar open-framework structure that is based on an octahedral topological motif. It forms from the polymerization of a single [Cd4Sn3Se13](6-) cluster which formally derives from a [Cd4Sn4Se17](10-) via elimination of one [SnSe4](4-) anion. K6Cd4Sn3Se13 exhibits facile ion-exchange properties with suitably sized cations.
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