期刊
TETRAHEDRON
卷 60, 期 23, 页码 5085-5092出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2004.04.004
关键词
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The nucleophilic addition of ethyl 3-propionylzinc iodide to a variety of differently protected pentopyranose derived D-glycals 6a-g proceeds with good to high levels of diastereoselectivity to provide the corresponding P-C-glycosides 7. The stereochemistry of the para-nitrobenzoate derivative 7d has been confirmed by X-ray crystallography, and the stereochemistry of the other P-C-glycoside products has been correlated to 7d. The stereochemical outcome observed supports the earlier suggestion by Isobe that through-space effects are important in stabilising and controlling the reactivity of the intermediate oxonium species represented by 11. (C) 2004 Elsevier Ltd. All rights reserved.
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