期刊
SYNTHETIC COMMUNICATIONS
卷 34, 期 12, 页码 2177-2184出版社
TAYLOR & FRANCIS INC
DOI: 10.1081/SCC-120038497
关键词
N-arylation; cupric acetate; tetraphenylborate salt; arylboronic acids; KF-alumina; microwaves
An experimentally simple microwave-assisted solvent-free N-arylation of primary amines with sodium tetraphenylborate or arylboronic acids, promoted by inexpensive cupric acetate, on the surface of KF-alumina is reported. The reaction is selective for mono-N-arylation, and a variety of functional groups are tolerated in the process.
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