期刊
COORDINATION CHEMISTRY REVIEWS
卷 248, 期 11-12, 页码 1025-1045出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2004.06.016
关键词
diruthenium tetracarboxylates; magnetism; mesogens; polymers; anticancer
The chemistry of diruthenium tetracarboxylates has grown substantially since our initial review in 1998. This update of the literature through 2003 covers the versatile synthetic aspects of the [Ru-2(mu-O2CR)(4)L-n](m+) (n = 1 or 2, m = 0-2) building block, for both mixed-valent Ru-2(II,III) and reduced Ru-2(II,II) cores, in which R can include a wide variety of alkyl, alkoxy, aryl, or metallocenyl groups (including chiral groups) with the axial L group normally being a neutral Lewis base or a halide but could also be a weakly coordinating counterion such as ClO4- or BF4-. The [Ru-2(mu-O2CR)(4)L-n](m+) unit has been linked together, through the judicious choice of axial or equatorial bridging ligands, into a variety of polymeric or network structures that display interesting magnetic, electronic, mesomorphic, occlusion and catalytic properties. The use of biologically relevant and/or hydrophilic R and L groups has also lead to the study of anti-tumor and anti-inflammatory properties. (C) 2004 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据