期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 346, 期 7, 页码 723-726出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200404018
关键词
asymmetric oxidation; homogeneous catalysis; kinetic resolution; sulfoxides; tandem process; titanium
A one-pot, titanium-catalyzed tandem sulfoxidation-kinetic resolution process, which combines asymmetric oxidation (at lower temperature) and kinetic resolution (at room temperature), has been developed. Excellent ees (up to > 99.9%) and higher chemical yields of sulfoxides were obtained and the results compared favorable with those from either oxidation or kinetic resolution.
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