期刊
SUPRAMOLECULAR CHEMISTRY
卷 16, 期 4, 页码 247-254出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/10610270410001663796
关键词
alkali metal ion; crown ether; crystal; self-assembly
Two novel supramolecular aggregations possessing column structures have been prepared from double-armed benzo-15-crown-5 ether (2) and its complex with potassium ion, respectively. Their molecular assembly behavior has been evaluated by calorimetry, H-1 NMR, X-ray crystallography and STM images, revealing that the molecular assembly behavior of 2 in the solid state can be controlled by the stepwise sandwiching complexation with the cation.
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