期刊
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
卷 65, 期 6, 页码 1121-1125出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jpcs.2003.11.039
关键词
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Dielectric properties and electrical conductivity of some conducting polypyrrole (PPy) composite films in the temperature range of 180300 K and in the frequency range of 20-10(5) Hz have been reported. The experimental dielectric data have been analyzed in the light of electric modulus formalism. The electric modulus representation shows well-defined relaxation peaks. The conductivity relaxation energy as well as the AC conductivity activation energy was found to decrease as the PPy content increased. The frequency-dependent conductivity behavior at different temperatures provides a qualitative description of the conduction mechanism. The relaxation, occurs as a result of the hopping of charge carriers between localized states and the correlated barrier hopping model, describes the dominant mechanism. (C) 2003 Elsevier Ltd. All rights reserved.
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