期刊
HYPERFINE INTERACTIONS
卷 156, 期 1, 页码 247-256出版社
SPRINGER
DOI: 10.1023/B:HYPE.0000043237.03194.72
关键词
cytochrome P450; peracetic acid; Mossbauer spectroscopy; high-field EPR
In this communication we present a complimentary Mossbauer- and EPR-study of the time dependance of the reaction of substrate free P450cam with peracetic acid within a time region ranging from 8 ms up to 5 min. An Fe(IV) species as well as a tyrosyl radical residing on the amino acid residue Tyr96 have been identified as reaction intermediates. These species possibly are formed by the reduction of compound I by means of transferring an electron from Tyr96 to the heme moiety.
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