期刊
CHEMISTRY OF MATERIALS
卷 16, 期 11, 页码 2194-2200出版社
AMER CHEMICAL SOC
DOI: 10.1021/cm0303540
关键词
-
Solid-state reactions between metal sulfates and metal oxides (assisted by K2CO3) have been used to prepare two classes of important perovskite materials: ferroelectric PbTiO3 and the catalyst/magnetic/fuel-cell material La1-xSrxMnO3 (x = 0.0 and 0.3). K2CO3 helps to drive the reaction by forming highly stable K2SO4 and CO2. Performing the reactions within solid monoliths and then dissolving out K2SO4 crystals in water permit macroporous materials to be obtained. The monoliths possess connected, open porosity with characteristic pore sizes of the order of 5-30 mum. Imprinted on this macroporous structure is a second, smaller scale of porosity arising from the sintering together of particles with sizes in the 100-300-nm range. The reaction pathways have been followed by thermodiffractometry, and the products characterized by Rietveld refinement of powder X-ray diffraction patterns, by scanning electron microscopy, and by dc magnetization measurements.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据