期刊
APPLIED ORGANOMETALLIC CHEMISTRY
卷 18, 期 6, 页码 277-281出版社
WILEY
DOI: 10.1002/aoc.634
关键词
iron complexes; biomimetic oxidation; pyridylbenzimidazole ligand; hydroxylation; ketonization
Complexes [Fe(Hpbi)(3)](ClO4)(2) (1) and [Fe(Hpbi)(3)](SbF6)(2) (2) (Hpbi = 2-(2-pyridyl)benzimidazole) were prepared by a modified method and characterized by IR, H-1 and C-13 NMR, mass spectrometry, electron paramagnetic resonance spectra and elemental analysis. The catalytic activities of 1 and 2 were evaluated for the oxidation of cyclohexene, cyclohexane, ethylbenzene and adamantane with tert-butylhydroperoxide or H2O2 as oxidant, and the results were compared with the properties of their analogue [Fe(bpy)(3)](SbF6)(2) (3). Complexes 1 and 2 both afforded the ketonization product for the oxidation of ethylbenzene and the hydroxylation product for adamantane. Copyright (C) 2004 John Wiley Sons, Ltd.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据