期刊
TETRAHEDRON LETTERS
卷 45, 期 24, 页码 4745-4748出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2004.04.069
关键词
nitroalkenes; Morita-Baylis-Hillman reaction; hydroxymethylation
The Morita-Baylis-Hillman reaction (MBHR) of conjugated nitroalkenes has been successfully carried out for the first time. A variety of aromatic and heteroaromatic nitroalkenes react with formaldehyde at room temperature in the presence of stoichiometric amounts of imidazole and catalytic amounts of anthranilic acid in THF providing moderate to good yields of the multifunctional adducts in most of the cases. (C) 2004 Elsevier Ltd. All rights reserved.
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