期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 11, 页码 2313-2320出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.200300940
关键词
electrochemistry; ionic liquids; packing efficiency; X-ray diffraction
The crystal structures of three very low-melting ionic liquid (IL) salts containing the 1-butyl-2,3-dimethylimidazolium cation and the fluoro anions BF4-, PF6- and SbF6- are reported. These are considered model compounds for ambient temperature ionic liquids, which are currently being explored as solvents for various types of synthetic reactions. All three compounds adopt significantly different structures in the solid state, highlighting the influence of counterion size in a series comprising a common cation. The crystal structures are discussed with respect to the possible existence of polar and non-polar domains, which are considered to be involved with the solvation of polar and non-polar substrates. The melting points of all three compounds are within the range 40-45 degreesC. A comparative measurement of conductivities of the molten salts in the vicinity of 20-50 degreesC has been made, including the new IL 1-allyl-2,3-dimethylimidazolium tetrafluoroborate and the widely applied 1-butyl-3-methylimidazolium tetrafluoroborate (BmimBF(4)). (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.
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