期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 11, 页码 2283-2288出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.200300780
关键词
tin; fluorine; anion carrier; NMR spectroscopy
The synthesis of bis[di-n-alkyl(fluoro)stannyl]methanes, [(R-2)FSn](2)CH2, (3, R n-octyl; 4, R = n-dodecyl), is reported and their unprecedented dimeric structure in solution with pentacoordinate tin atoms is rationalized on the basis of F-19 and Sn-119 NMR spectroscopy, osmometric molecular mass determination and electrospray mass spectrometry (ESMS). F-19 and Sn-119 MAS NMR and Mossbauer spectroscopy also indicate pentacoordinate tin atoms for the solid state. The ability Of compounds 3 and 4 to bind fluoride ion selectively and reversibly is evaluated through potentiometric measurements. Compared with the previously reported organotin(IV)based fluoride ionophore [Cl(Ph-2)Sn](2)CH2, 3 and 4 exhibit a drastically improved lifetime, while retaining their high preference for fluoride over all other lipophilic anions evaluated. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004).
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