期刊
MOLECULAR PHYSICS
卷 102, 期 11-12, 页码 1367-1376出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/00268970410001728555
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Hyperfine structure is observed on several infrared transitions to the I-5(7) and I-5(6) multiplets of the Ho3+ C-4v centre in CaF2. Particularly complex and detailed hyperfine structures are observed for transitions to the Y-3 level of the I-5(7) multiplet, which include the appearance of DeltaI(z) not equal 0 transitions. The hyperfine lines of this level are satisfactorily accounted for by strong mixing of close-lying levels of this multiplet by the perpendicular hyperfine interaction, which leads to relaxation of the DeltaI(z) = 0 selection rule and a redistribution of the hyperfine intensities over many transitions. An excellent correspondence is found between the measured and simulated spectra.
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