期刊
JOURNAL OF PHYSICAL CHEMISTRY B
卷 108, 期 23, 页码 7723-7727出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp049512g
关键词
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In the present article, we discuss the results of investigations of the influence of hydrostatic pressure (up to 1.2 GPa) on the spin transition behavior in [Fe(phen)(2)(NCS)(2)] polymorph II and [CrI2(depe)(2)]. It is demonstrated that pressure effect studies are very helpful in elucidating the mechanism of cooperative dynamic electronic structure phenomena accompanied by significant volume changes. Application of hydrostatic pressure serves as a tool for modifying the ligand field strength in a controlled manner.
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