期刊
CHEMICAL PHYSICS LETTERS
卷 391, 期 4-6, 页码 334-337出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cplett.2004.04.113
关键词
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The primary reaction products from 248-nm chlorine azide photolysis are identified in a collision-free experiment. In contrast to all previous reports, the radical channel producing Cl + N-3 (95 +/- 3%) is seen to dominate the photochemistry. The molecular channel producing NCl + N-2 (5 +/- 3%) was also observed. (C) 2004 Elsevier B.V. All rights reserved.
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