期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 69, 期 13, 页码 4441-4445出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo049708c
关键词
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Natural glycopeptides and glycoproteins exhibit a large structural diversity, which can be mimicked by synthetic glycopeptide derivatives to assist the investigation of biological functions and structure-activity relationships. Here, dendronized saccharides were synthesized to provide glycosyl amino acids, equipped with a branching element for the preparation of branched glycopeptide mimetics. An optimized Staudinger-type reaction served as key reaction en route to the complex glycopeptide 14, in which three mannose moieties were connected to the branched glucuronyl scaffold.
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