期刊
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY
卷 110, 期 1, 页码 27-31出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.mseb.2004.01.020
关键词
CuO additive; low temperature sintering; PZN-PZT; Jahn-Teller effect; piezoelectric properties
Low temperature sintering of 0.5 wt.% MnO2-added Pb((Zn1/3Nb2/3)(0.20) (Zr0.50Ti0.50)(0.80))O-3 ceramics (PZNT) was investigated using CuO as sintering aids. It was found that the addition of CuO significantly improved the sinterability of PZNT ceramics, resulting in a reduction of sintering temperature from 1050 to 900 degreesC. The CuO addition also influences in a pronounced way both the crystal structure and microstructure of the low temperature sintered PZNT materials. The materials are transformed from the tetragonal to the rhombohedral structure, and the grain sizes are decreased when CuO are added. The distortion of crystal structure for PZNT samples with CuO addition can be explained with Jahn-Teller effect for electron state d(9) Of Cu2+ ion. On the other hand, with the increasing of CuO addition, k(p), d(33) were slightly decreased, but Q(m) and tan delta were optimized at 1.5 wt.% CuO. (C) 2004 Elsevier B.V. All rights reserved.
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