期刊
APPLIED SURFACE SCIENCE
卷 459, 期 -, 页码 292-299出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apsusc.2018.08.002
关键词
CO2 photoreduction; Tetra(4-carboxyphenyl)porphyrin iron(III) chloride; CdS; Ethylenediamine functionalization; Charge transfer channel
类别
资金
- National Natural Science Foundation of China [21673052]
- Ministry of Science and Technology of China [2015DFG62610, 2013CB834800]
- Belt and Road Initiative and the Strategic Priority Research Program by Chinese Academy of Sciences
The hybrid coupling between inorganic semiconductor and molecular catalyst can provide a promising approach for the construction of highly efficient and selective photocatalytic CO2 reduction systems. This hybrid system can take full advantage of the strong light harvesting capability of semiconductor and high selectivity of molecular catalyst. The interaction linker bridging the semiconductor and molecular catalyst plays an important role in supplying efficient electron transfer channels. In this study, both CdS with and without ethylenediamine functionalization (i.e., CdS-EF and CdS) have been successfully synthesized and further respectively coupled with tetra(4-carboxyphenyl)porphyrin iron(III) chloride (FeTCPP) for CO2 photoreduction. It is found that CdS-EF exhibits inferior photocatalytic activity to CdS, while CdS-EF/FeTCPP hybrid photocatalyst shows much higher activity than CdS/FeTCPP. This is because hydrogen bonding exists between the amino groups in CdS-EF and carboxyl groups in FeTCPP, which can act as electron transfer channels from CdS to FeTCPP in the obtained hybrid system.
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